Lithium batteries don’t need to be warm for discharge (generally and with an asterisk), it’s charging. Discharge while freezing causes slower chemical reactions (aka lower discharge current), but that is rarely a huge problem compared to the charging problem.
Any charging around or below freezing causes pretty quick destruction of the cells as the chemistry switches to a more favorable destructive one way electroplating process instead of the desirable (and reversible) ion exchange process.
A common engineering solution to this has started to be temperature dependent shunts that route charging energy to heating pads around the battery until the battery temp gets above a certain safe point.
It adds complexity, cost, and adds several undesirable failure mode however, and Lithium battery cost is already a major factor in these systems, so if you’re in a situation where you can’t reliably temperature control your batteries (cold climate, non-conditioned battery space), lead acid is still a very viable and often desirable chemistry instead.
Round trip efficiency isn’t great with them, and you have to way over provision to get good cell lifespan, but it works.
Any charging around or below freezing causes pretty quick destruction of the cells as the chemistry switches to a more favorable destructive one way electroplating process instead of the desirable (and reversible) ion exchange process.
A common engineering solution to this has started to be temperature dependent shunts that route charging energy to heating pads around the battery until the battery temp gets above a certain safe point.
It adds complexity, cost, and adds several undesirable failure mode however, and Lithium battery cost is already a major factor in these systems, so if you’re in a situation where you can’t reliably temperature control your batteries (cold climate, non-conditioned battery space), lead acid is still a very viable and often desirable chemistry instead.
Round trip efficiency isn’t great with them, and you have to way over provision to get good cell lifespan, but it works.